Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures

2015-08-13 626 0人评论
1. Research Background
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
2. Research Content and Results
Test Materials
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Test Methods
Basic Sample Parameters:
Dry Density: 1.9 g/cm3
Bentonite Content: 70%
Diameter: 50 mm
Height: 150 mm
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Test Results
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
•The hydration rate of the sample decreases with increasing distance from the water injection end
•Compared with distilled water, the lead nitrate solution permeates faster
•The total axial strain is greater than the vertical swelling strain at different positions
•The closer to the water injection end, the greater the swelling deformation
 
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
•The vertical swelling deformation is greater than the horizontal swelling deformation
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
 •Most of the Pb(2+) is adsorbed and immobilized at the water injection end of the sample
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
 •Hydration is more complete near the water injection end, resulting in an increase in small pores and a decrease in large pores
Migration of Lead Ions in Unconfined Highly Compacted Bentonite-Sand Mixtures
3. Main Conclusions
  1) The hydration rate of the GMZ bentonite-sand mixture decreases significantly with increasing distance from the water injection end. Compared with distilled water, the chemical solution permeates faster in the sample, mainly due to the inhibitory effect of solution ions on the thickness of the double electric layer.

2) The axial swelling strain of the mixture reaches as high as 7.57%, while the radial swelling strain is relatively small. Moreover, compared with the vertical direction, the horizontal swelling strain at the same distance is smaller.

3) The GMZ bentonite-sand mixture can use its strong adsorption capacity to immobilize Pb(2+) at the water injection end of the sample and prevent it from further diffusing into the interior of the sample.

4) The closer the sample is to the water injection end, the more complete the hydration, which leads to a significant decrease in large pores and a marked increase in small pores.
(Source: Department of Geotechnical Engineering, Tongji University, Jia Lingyan)

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